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Difference Between Alpha and Beta Elimination Reaction

October 5, 2020Posted byMadhu

Thekey differencebetween alpha and beta elimination reaction is thatin alpha elimination reaction, two leaving groups leave from the same atom whereas, in beta elimination reaction, the two leaving groups leave from two adjacent atoms of the same molecule.

Elimination reaction is a type of organic reaction in which two substituents are removed from a molecule. This removal is done either in a single step reaction or in a two-step mechanism. The single-step mechanism is denoted as anE2 reactionwhile the two-step mechanism is denoted asE1 reaction. In these denotations, the number that comes with the letter E refers to the kinetics of the reaction, e.g. E2 reactions are双分子的反应(second-order) while E1 reactions areunimolecular reactions(first-order). In addition to that, there are two types of elimination reactions named as alpha elimination and beta elimination, the latter being the most common elimination reaction type.

CONTENTS

1.Overview and Key Difference
2.What is an Alpha Elimination Reaction
3.What is a Beta Elimination Reaction
4.Side by Side Comparison – Alpha vs Beta Elimination Reaction in Tabular Form
5.Summary

What is an Alpha Elimination Reaction?

Alpha elimination reaction is a type of organic reaction in which two leaving groups leave from the same atom in the molecule. It is the second most common type of elimination reaction and is denoted by α–elimination. When there is a carbon centre in the molecule that undergoes the elimination reaction, the final result is the formation of a carbene, which includes stable carbenes such as carbon monoxide and isocyanides. For example, alpha elimination of chloroform molecule, CHCl3, in the presence of a strong base gives dichlorocarbene along with HCl as the eliminating compound or the leaving group. In this reaction, there is one carbon centre containing three chlorine atoms and a hydrogen atom attached to it. Elimination occurs at this one carbon atom; leaving groups are hydrogen atom and one chlorine atom.

Difference Between Alpha and Beta Elimination Reaction

Figure 01: Examples of Alpha and Beta Elimination Reactions

Similarly, formic acid also can undergo alpha elimination. The stable products of this elimination reaction include water and carbon monoxide in the presence of an acidic condition. Moreover, an alpha elimination can occur in a metal centre, which can lead to the lowering of the metal oxidation state and the coordination number by 2 units. Hence, this type of reaction is named asreductive elimination.

What is a Beta Elimination Reaction?

Beta elimination reaction is a type of organic chemistry in which two groups leave from two adjacent carbon atoms. In other words, beta elimination is the loss of electrofuge and nucleofuge on vicinal carbons. This is the most common type of elimination reaction in organic chemistry.

这个反应的最终产物,β从而取消ion forms a product containing C=C and C=X bonds. When considering the stability of the final product and orbital alignment, the beta elimination reaction is strongly favourable than other types of elimination reactions. However, there are other types such as alpha elimination and gamma elimination for the systems that do not favour the alpha elimination.

What is the Difference Between Alpha and Beta Elimination Reaction?

Alpha and beta elimination are two types of organic chemical reactions. The key difference between alpha and beta elimination reaction is that in alpha elimination reaction, two leaving groups leave from the same atom whereas, in beta elimination reaction, the two leaving groups leave from two adjacent atoms of the same molecule.

Below infographic tabulates the differences between alpha and beta elimination reaction in more detail.

Difference Between Alpha and Beta Elimination Reaction in Tabular Form

Summary – Alpha vs Beta Elimination Reaction

Alpha and beta elimination are two types of organic chemical reactions. The key difference between alpha and beta elimination reaction is that in alpha elimination reaction, two leaving groups leave from the same atom whereas, in beta elimination reaction, the two leaving groups leave from two adjacent atoms of the same molecule.

Reference:

1. “β-Elimination Reactions.”Chemistry LibreTexts2020年8月15日,LibretextsAvailable here.
2. “1,1-Elimination.”Chemistry LibreTexts, Libretexts, 24 Aug. 2020,Available here.
3. “Elimination Reaction.”Wikipedia, Wikimedia Foundation, 21 Sept. 2020,Available here.

Image Courtesy:

1. “Eliminationrxns” By Alsosaid1987 – Own work(CC BY-SA 4.0)viaCommons Wikimedia

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Filed Under:Organic Chemistry

About the Author:Madhu

Madhu is a graduate in Biological Sciences with BSc (Honours) Degree and currently persuing a Masters Degree in Industrial and Environmental Chemistry. With a mind rooted firmly to basic principals of chemistry and passion for ever evolving field of industrial chemistry, she is keenly interested to be a true companion for those who seek knowledge in the subject of chemistry.

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