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碳酸锂和氢氧化锂有什么区别

2021年11月14日Posted byMadhu

Thekey difference between lithium carbonate and lithium hydroxideis that碳酸锂含有一个与两种锂阳离子相关的碳酸根阴离子,而氢氧化锂含有一种与一个氢氧化阴离子相关的锂阳离子。

碳酸锂和氢氧化锂useful in producing cathode material forlithium-ionbatteries. However, there are few differences between these two substances.

CONTENTS

1.Overview and Key Difference
2.What is Lithium Carbonate
3.What is Lithium Hydroxide
4.Lithium Carbonate vs Lithium Hydroxide in Tabular Form
5.Summary – Lithium Carbonate vs Lithium Hydroxide

What is Lithium Carbonate?

Lithium carbonate is an inorganic compound having the chemical formula Li2CO3. It is the lithium salt ofcarbonic acid. It appears as a white powder that is odorless. It has many applications in the processing ofmetal oxidesand is also useful as a drug in treating mood disorders. For example, it is one of the most important drugs used in treating bipolar disorder.

Lithium Carbonate and Lithium Hydroxide - Side by Side Comparison

Figure 01: The Crystal Structure of Lithium Carbonate

In industrial applications, lithium carbonate is very important as a precursor for compounds we use in making lithium-ion batteries. Furthermore, glasses that are made from lithium carbonate are very important in ovenware production. We can find this compound as a common ingredient in both low-fire and high-fire ceramic glaze. It can form low-melting fluxes along with silica and other materials. Furthermore, the alkaline properties of lithium carbonate cause the change of state of metal oxide colorants in the glaze. E.g. red iron oxide. Apart from that, cement tends to set more rapidly when it is prepared with lithium carbonate.

What is Lithium Hydroxide?

Lithium hydroxide is an inorganic compound having the chemical formula LiOH. There are two forms; they are the hydrated form and the anhydrous form. The number of water molecules in the hydrated form can differ. Both hydrated and anhydrous forms are hygroscopic solids that are soluble in water and slightly soluble in ethanol. Moreover, both these forms are commercially available for different applications. We can classify it as a strong base. However, it is the weakest alkali metal hydroxide known up to now.

Lithium Carbonate vs Lithium Hydroxide in Tabular Form

图02:氢氧化锂的晶体结构

The hard rock spodumene is the feedstock used for the production of lithium hydroxide. This compound has its lithium content expressed as a percentage of lithium oxide. Often, the production of lithium hydroxide is done using metathesis reactions using calcium hydroxide. As an alternative route, we can use lithium sulfate.

There are many important uses of lithium hydroxide, including the production of lithium-ion batteries, as a grease thickener, in breathing gas purification systems for spacecraft, as intermediates for the production of other lithium-containing compounds, in the production of ceramics for the alkalization, etc.

碳酸锂和氢氧化锂有什么区别?

碳酸锂和氢氧化锂useful in producing cathode material for lithium-ion batteries. However, there are few differences between lithium carbonate and lithium hydroxide. Among them, the key difference between lithium carbonate and lithium hydroxide is that lithium carbonate contains one carbonate anion associated with two lithium cations whereas lithium hydroxide contains one lithium cation associated with one hydroxide anion. In addition,lithium carbonate is less expensive than lithium hydroxide.

Summary – Lithium Carbonate vs Lithium Hydroxide

碳酸锂和氢氧化锂是重要的无机化合物。碳酸锂和氢氧化锂之间的关键区别在于碳酸锂含有一个与两种锂阳离子相关的碳酸根阴离子,而氢氧化锂含有一种与一个氢氧化阴离子相关的锂阳离子。此外,lithium carbonate is less expensive than lithium hydroxide.

Reference:

1. “Lithium Carbonate.”概述|ScienceDirect主题.

Image Courtesy:

1. “Lithium-carbonate-xtal-1979-Mercury-3D-sf” By Ben Mills – Own work (Public Domain) via Commons Wikimedia
2. “Lithium-hydroxide-xtal-3D-SF” By CCoil (talk) – Own work(CC BY 3.0)via Commons Wikimedia

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Filed Under:无机化学

About the Author:Madhu

Madhu毕业于具有文学学士学位(荣誉)学位的生物科学,目前是工业和环境化学硕士学位。她的思维牢固地扎根于化学基本原理和对不断发展的工业化学领域的热情,她非常有兴趣成为那些在化学方面寻求知识的人的真正伴侣。

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