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共轭酸和共轭碱之间的差异

October 23, 2011Posted byMadhu

Thekey differencebetween conjugate acid and conjugate base is thatconjugate acids donate protons, whereas conjugate bases accept protons.

In 1923, two scientists, Bronsted and Lowry presented a theory on acid-base behaviour. According to Bronsted – Lowry theory, anacidis a proton donor, and a base is a proton acceptor. Therefore, a molecule to behave as an acid should encounter a proton acceptor. On the other hand, a molecule to behave as a base it should encounter a proton donor. Therefore, for an acid-base reaction, both proton donors and acceptors should be there. However, water can act as both acid and base. When water accepts a proton, it forms ahydronium ion, and when it donates a proton, it produces ahydroxideion.

CONTENTS

1.Overview and Key Difference
2.What is Conjugate Acid
3.What is Conjugate Base
4.Side by Side Comparison – Conjugate Acid vs Conjugate Base in Tabular Form
5.概括

什么是共轭酸?

Conjugate acid is a substance made from a base. When a base accepts a proton from another molecule, it forms a conjugate acid. Conjugate acid can remove the electron and return to the parent base. Thus, conjugate acids have acidic properties.

共轭酸和共轭碱之间的差异

Figure 01: Formation of Conjugate Acid and Conjugate Base

For example, we can consider the situation where ammonia dissolves in water.

NH3+ H2O ⇌ NH4++哦–

In the above example, ammonium ion is the conjugate acid of ammonia. Likewise, when considering the backward reaction, water is the conjugate acid of hydroxide base.

What is Conjugate Base?

Conjugate base is a substance that forms after an acid gives up a proton to a base. But, this can accept a proton again; thus, it has basic characteristics. The potential proton acceptor formed from the parent acid is the conjugate base. When the conjugate base accepts a proton, it is reverse to the parent acid again.

Besides, many solvents can act as proton donors or acceptors. Therefore, they can induce the acidic or basic behaviour in solutes. For example, when ammonia dissolves in water, water acts as the acid and gives a proton to ammonia, and thus, forming an ammonium ion. Meanwhile, the water molecule is converted to a hydroxide anion. Here, the conjugate base of the water is the hydroxide anion. And the conjugate base of the ammonium is ammonia.

What is the Difference Between Conjugate Acid and Conjugate Base?

The key difference between conjugate acid and conjugate base is that conjugate acids can donate protons, whereas conjugate bases can accept protons. Moreover, conjugate acids are formed from bases; conversely, conjugate bases are formed from acids. However, the conjugate acids and bases that form in a spontaneous reaction are much weaker than their parent molecules.

共轭酸和共轭碱之间的差异in Tabular Form

概括– Conjugate Acid vs Conjugate Base

Conjugate acid and conjugate base are a pair of chemical species that has opposite chemical behaviour. The key difference between conjugate acid and conjugate base is that conjugate acids can donate protons, whereas conjugate bases can accept protons.

Reference:

1.Libretexts。“11.12:共轭酸碱对。”Chemistry LibreTexts, National Science Foundation, 26 Nov. 2018.Available here

Image Courtesy:

1.”Conjugate base reaction”By Schlenk(CC BY-SA 3.0)viaCommons Wikimedia

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Filed Under:Analytical Chemistry

About the Author:Madhu

Madhu毕业于具有文学学士学位(荣誉)学位的生物科学,目前是工业和环境化学硕士学位。她的思维牢固地扎根于化学基本原理和对不断发展的工业化学领域的热情,她非常有兴趣成为那些在化学方面寻求知识的人的真正伴侣。

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