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脂肪族和芳香族Polyuret之间的区别hane

2020年8月25日Posted byMadhu

Thekey differencebetween aliphatic and aromatic polyurethane is thataliphatic polyurethane contains a chain structure whereas aromatic polyurethane contains a ring structure.

聚氨酯或PUR是最大的聚合物类,具有可以根据应用而更改的特性。这些材料可以是thermosetting or thermoplastic. Also, they can be rigid, soft, or flexible, depending on the chemicals structure. A polyurethane polymer forms from the reaction between an organic diisocyanate and a diol compound.

CONTENTS

1.Overview and Key Difference
2.What is Aliphatic Polyurethane
3.What is Aromatic Polyurethane
4.Side by Side Comparison – Aliphatic vs Aromatic Polyurethane in Tabular Form
5.概括

什么是脂肪族聚氨酯?

脂肪族聚氨酯或脂肪族丙烯酸聚氨酯是没有芳族结构的聚合物材料。作为工业和建筑应用中的涂层,它很重要。该聚合物材料的化学结构很重要,因为该材料坚固而柔韧。因此,该材料是许多产品获得耐用饰面的添加剂。最常见的是,该材料用于用于外部用途的密封胶和涂料。

When considering the chemical makeup of aliphatic polyurethane, it contains long chains of repeating molecules. Since these chain structures can be chemically manipulated to be more or less flexible and strong, this material is versatile. The term aliphatic refers to the composition of open-chain hydrocarbons.

此外,这种材料会变干成艰难的饰面,并且对水和紫外线都具有很高的抵抗力。因此,这种材料在暴露于阳光时不会变黄。同样,该材料具有高抗拉强度并缓慢流动。因此,我们可以轻松地将此材料用作涂层(作为厚膜)。因为这种材料很容易与epoxy, we can easily apply it on epoxy as a sealant. Moreover, this material is commercially available in gloss or matt finish and in various colors.

What is Aromatic Polyurethane?

Aromatic polyurethane is a polymer material containing cyclic, aromatic structures. The structure of aromatic polyurethane differs from aliphatic polyurethane according to the structure of the isocyanate used in the production. If the isocyanate is aromatic, then the polymer material becomes aromatic. The most common aromatic isocyanates are toluene diisocyanate (TDI), diphenylmethane diisocyanate (MDI), and naphthalene diisocyanate (NDI). Here, toluene diisocyanate is usually used as a mixture of twoisomers. Often, TDI and MDI are used for the production of thermoplastic elastomers and foams, but their polymeric forms are used for coatings, sealants, and adhesives.

脂肪族和芳香族Polyuret之间的区别hane

Figure 01: Synthesis of Aromatic Polyurethane

Aromatic polyurethane has a high glass transition temperature. They are rather brittle, whereas aliphatic polyurethane has a low glass transition temperature and is flexible.

What is the Difference Between Aliphatic and Aromatic Polyurethane?

The key difference between aliphatic and aromatic polyurethane is that aliphatic polyurethane contains a chain structure whereas aromatic polyurethane contains a ring structure. Therefore, aliphatic polyurethane does not contain aromatic rings while aromatic polyurethane contains aromatic rings. Furthermore, the aromatic polyurethane has a high glass transition temperature and is rather brittle, whereas aliphatic polyurethane has a low glass transition temperature and is flexible.

The following table shows more differences between aliphatic and aromatic polyurethane.

脂肪族和芳香族Polyuret之间的区别hane in Tabular Form

概括– Aliphatic vs Aromatic Polyurethane

The key difference between aliphatic and aromatic polyurethane is that aliphatic polyurethane contains a chain structure whereas aromatic polyurethane contains a ring structure. Moreover, aromatic polyurethane has a high glass transition temperature and is rather brittle, while aliphatic polyurethane has a low glass transition temperature and is flexible.

Reference:

1. “What Is Aliphatic Acrylic Polyurethane?”Hunker,Available here.

Image Courtesy:

1. “Polyurethane synthesis” By Hbf878 – Own work, remade based on File:Polyurethane.png by zh:User:Cyfer(CC BY-SA 3.0)viaCommons Wikimedia

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Filed Under:Polymer Chemistry

About the Author:Madhu

Madhu毕业于具有文学学士学位(荣誉)学位的生物科学,目前是工业和环境化学硕士学位。她的思维牢固地扎根于化学基本原理和对不断发展的工业化学领域的热情,她非常有兴趣成为那些在化学方面寻求知识的人的真正伴侣。

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