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Difference Between Primary and Secondary Standard Solution

June 18, 2018Posted byMadhu

Thekey difference在初级和次级标准解决方案之间是主要标准solutionhas a high purity and less reactivity whereas secondary solution has a less purity and high reactivity.

Standardization is the process of finding the exact concentration of a prepared solution using a standard solution as the reference. Standard solutions have accurately known concentrations and we prepare these solutions using standard substances. The two major standard solution forms are primary standards and secondary standards. We use primary standards for the standardization of secondary standard solutions. Secondary standards are useful for specific analytical experiments.

CONTENTS

1.Overview and Key Difference
2.What is Primary Standard Solution
3.What is Secondary Standard Solution
4.Side by Side Comparison – Primary vs Secondary Standard Solution in Tabular Form
5.概括

What is Primary Standard Solution?

Primary standard solutions the solutions made form primary standard substances. These substances have a high purity which nearly equals 99.9% purity. We can dissolve this substance in a known volume of solvent in order to obtain the primary standard solution. These solutions can involve chemical reactions. Therefore, we can use this reagent to determine the unknown concentration of a solution that undergoes a particular chemical reaction.

These solutions have specific chemical and physical properties. For example, these solutions have a high purity and are highly stable. Intitrations,在进行实验之前,我们应该标准化用于滴定的所有解决方案。这是因为,即使我们采用确切的物质来制造这些解决方案,它们也可能没有我们期望的确切浓度,因为这些物质并不那么纯净。一些主要标准的例子包括溴酸钾(KBRO3),氯化钠,锌粉,等

What is Secondary Standard Solution?

Secondary standards solutions are the solutions made from secondary standard substances. We prepare these solutions for a specific analytical experiment. We should determine the concentration of these solutions using primary standards. Most of the times, these solutions are useful for the calibration of analytical instruments.

Difference Between Primary and Secondary Standard Solution

Figure 01: Potassium Permanganate

However, the purity of these solutions is less compared to primary standards and the reactivity is high. Due to this high reactivity, these solutions get contaminated easily. Some common examples are anhydrous sodium hydroxide and potassium permanganate. These compounds are吸湿性.

主要标准解决方案和次要标准解决方案有什么区别?

Primary standard solution is the solution made form primary standard substances. It has a high purity and a low reactivity. Secondary standards solutions are the solutions made from secondary standard substances. These are less pure and highly reactive. This is the main difference between primary and secondary standard solution. Furthermore, due to their low reactivity, primary standard solutions rarely get contaminated whereas as secondary standards solutions are highly reactive, they easily get contaminated. Therefore, we should standardize secondary standards solutions before use.

Difference Between Primary and Secondary Standard Solution in Tabular Form

摘要 - 初级和次要解决方案

Standard solutions are important in determining the unknown concentrations of experimental solutions. There are two forms as primary standards and secondary standards. The difference between primary and secondary standard solutions is that primary standard solutions have a high purity and less reactivity whereas secondary solutions have a less purity and high reactivity.

Reference:

1. Helmenstine, Anne Marie, Ph.D. “What Is a Primary Standard in Chemistry?” ThoughtCo, Apr. 18, 2018.Available here
2. International Union. “Standard Solution.” IUPAC Gold Book – Capillary Condensation.Available here

Image Courtesy:

1.Potassium-permanganate-solution’ By Benjah, Armando-Martin(CC BY-SA 3.0)通过Commons Wikimedia

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Filed Under:Analytical Chemistry

About the Author:Madhu

Madhu毕业于具有文学学士学位(荣誉)学位的生物科学,目前是工业和环境化学硕士学位。她的思维牢固地扎根于化学基本原理和对不断发展的工业化学领域的热情,她非常有兴趣成为那些在化学方面寻求知识的人的真正伴侣。

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